Magnetic characterization of microcrystalline Na3Ln0.99−xEr0.01Crx(PO4)2 orthophosphates synthesized by Pechini method (Ln = La, Gd)
Sławomir M. Kaczmarek , Grzegorz Leniec , Hubert Fuks , Tomasz Skibiński , Aleksandra Pelczarska , Patrycja Godlewska , Jerzy Hanuza , Irena Szczygieł
AbstractNa3Ln(PO4)2 orthophosphates (Ln = La, Gd) doped with Er3+ and co-doped with Cr3+ ions were synthesized by Pechini method and characterized by electron paramagnetic resonance (EPR) and magnetic susceptibility measurements. Low temperature EPR spectra were detected and analyzed in terms of temperature dependence and the structure of the obtained materials. They show that erbium and chromium ions substitute Ln3+ and also Na+ ions or Na+ channels forming complex EPR spectra. Both kinds of ions reveal ferromagnetic type of interaction which shows some anomaly at the temperature between 10 K and 15 K. Magnetic susceptibility reveals a weak antiferromagnetic kind of interaction dominating in the whole temperature range, from 3.5 to 300 K.
|Journal series||Materials Science-Poland, ISSN 2083-1331, e-ISSN 2083-134X , (A 15 pkt)|
|Publication size in sheets||0.6|
|Keywords in English||orthophosphates, erbium, chromium, EPR technique, magnetization measurements|
|Publication indicators||= 1; = 1|
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