The mechanism of X-ray excited luminescence in BaHfO3 doped with Eu3+, Y3+ or Eu3+, La3+
Anna Dobrowolska , Eugeniusz Zych
AbstractLuminescent properties of BaHfO3:Eu codoped with Y3+ and La3+ were investigated. It was found that the codopants influence the location of Eu3+ in the host lattice. Y3+ directs Eu3+ into Ba2+ and La3+ channels Eu3+ into Hf4+ site. The mechanism of the process is discussed. Both, Eu'(Hf) and E(u) over dot(Ba) show photoluminescence but only the former one exhibits X-ray excited luminescence. This phenomenon is explained based on the electronic structure of BaHfO3 host.
|Journal series||Journal of Luminescence, ISSN 0022-2313, e-ISSN 1872-7883, (A 35 pkt)|
|Publication size in sheets||0.5|
|Keywords in English||4F-Electron Binding-Energies; Inorganic-Compounds; 1st Principles; Cubic Bahfo3; Band; States; Host|
|ASJC Classification||; ; ; ;|
|Score|| = 35.0, 03-02-2019, ArticleFromJournal|
= 35.0, 03-02-2019, ArticleFromJournal
|Publication indicators||: 2016 = 1.14; : 2017 = 2.732 (2) - 2017=2.577 (5)|
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